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Consecutive solvent – C60 exchange on (η2– C60) Ir(CO)Cl(PPh3)2 and catalytically significant organometallic reactions on Ir(CO)(PPh3)2Cl(Solvent)
(2010)
The solvent/C60 exchange reactions on (η2 – C60)Ir(CO)(PPh3)2Cl (solvent = benzene and cyclohexane) are biphasic. Plots of absorbance values at 550 nm vs. time are biexponential. Experiments where the reactions were monitored ...